Prof. Dr. Dr. h. c. mult. Herbert W. Roesky |
Professor Roesky widmet seine Zeit sowohl der wissenschaftlichen Forschung, als auch der Verbreitung der Wissenschaft ansich und der Chemie im Speziellen. Er ist aufgrund der Qualität seiner wissenschaftlichen Veröffentlichungen (über 700 Veröffentlichungen in international renomierten Zeitschriften) und seiner Beiträge zur wissenschaftlichen Bildung für Jeden ein Begriff.
Seine Forschungsgruppe (ca. 30 Mitglieder) setzt sich aus Diplomanden, Doktoranden, Post-Doktoranden und wissenschaftlichen Mitarbeitern aus der ganzen Welt zusammen.
Die Forschungsinteressen von Prof. Roeskys Gruppe sind weit gefächert, dies spiegelt sich insbesondere in den vielfältigen Beiträgen auf dem Gebiet der anorganischen Synthese, der Katalyse und der Materialwissenschaften wieder.
Auf den verschiedensten Gebiete wie organometallische Fluoride, Metallasiloxane, Metallazyclen, Metallaphosphonate, Alumoxane, Hauptgruppen- und Übergangsmetallcluster und Koordinationspolymere wird derzeit Forschung betrieben.
In den letzten Jahren wurden vielfältige Anstrengungen unternommen, Probleme aus dem Bereich der Katalyse zu lösen. Besondere Schwerpunkte bildeten die Entwicklung von Katalysatoren für die Hydroformylierung (in Ein- und Zweiphasensystemen), die Oxidation und Epoxidierung sowie die Polymerisation.
Verschiedene Precursor (einschliesslich Single-Source) wurden in den letzten Jahren in dieser Forschungsgruppe entwickelt; Filme von blauem-BN, Bor-Reichem-BN, GaN und CdSe wurden unter Anwendung der Dampfphasenabscheidung zur Bildung von dünnen Schichten verwendet.
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Neculai,
Ana Mirela; Neculai, Dante; Nikiforov, Grigori B.; Roesky, Herbert W.;
Schlicker, Christine; Herbst-Irmer, Regine; Magull, Joerg; Noltemeyer,
Mathias. Partially fluorinated rare earth metal complexes.
European Journal of Inorganic Chemistry (2003),
(17), 3120-3126. CODEN: EJICFO ISSN:1434-1948. AN 2003:745222 CAPLUS (Copyright 2003 ACS on SciFinder (R))
Zhu, Hongping; Chai, Jianfang; Roesky, Herbert W.;
Noltemeyer, Mathias; Schmidt, Hans-Georg; Vidovic, Denis; Magull, Joerg. A bulky chelating diamidoaluminum
monohydride - synthesis, structure and reactions with Me3SnF and heavy group 16
elements. European
Journal of Inorganic Chemistry
(2003), (17), 3113-3119. CODEN: EJICFO ISSN:1434-1948.
AN
2003:745221
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Rong, Junfeng; Peng, Ying; Roesky, Herbert W.; Li,
Jiyang; Vidovic, Denis; Magull, Joerg.
The first structurally characterized aluminum squaraine complex:
L2(AlMe2)4×2THF×2toluene [L = bis(2,6-diisopropylanilino)squaraine].
European Journal of Inorganic Chemistry (2003),
(17), 3110-3112. CODEN: EJICFO ISSN:1434-1948. AN 2003:745220 CAPLUS (Copyright 2003 ACS on SciFinder (R))
Nikiforov, Grigori B.; Roesky, Herbert W.; Vidovic,
Denis; Magull, Joerg. Synthesis
and structure of the heterobimetallic Yb(II) complex of composition L2Yb2LiI3
supported with the b-diketiminato
ligand [L=Et2NCH2CH2NC(Me)CHC(Me)NCH2CH2NEt2].
Journal of Molecular Structure
(2003), 656(1-3), 155-160. CODEN: JMOSB4 ISSN:0022-2860.
AN
2003:645946
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Schiefer,
Marcus; Reddy, N. Dastagiri; Roesky, Herbert W.; Vidovic, Denis. Synthesis and Structural Characterization of an
Exclusively N-Based Tetrameric Aluminum(I) Compound.
Organometallics
(2003), 22(18), 3637-3638. CODEN: ORGND7
ISSN:0276-7333. AN 2003:600152 CAPLUS (Copyright 2003 ACS on SciFinder (R))
Pinkas, Jiri; Roesky, Herbert W.. Organoaluminum fluorides. Journal of Fluorine
Chemistry (2003), 122(2), 125-150. CODEN:
JFLCAR ISSN:0022-1139. AN 2003:580597 CAPLUS (Copyright 2003 ACS on SciFinder (R))
Nikiforov, Grigori B.; Roesky, Herbert W.; Magull,
Jorg; Labahn, Thomas; Vidovic, Denis; Noltemeyer, Mathias; Schmidt, Hans-Georg;
Hosmane, Narayan S. Synthesis
and investigation of the stability of Ti(III) b-diketiminato complexes. Structure of the tetrameric
non-metallocene titanium fluoride complex (L2)4Ti4F6O2×2toluene supported by the b-diketiminato ligand.
Polyhedron (2003), 22(19), 2669-2681.
CODEN: PLYHDE
ISSN:0277-5387. AN
2003:578995 CAPLUS (Copyright 2003 ACS on SciFinder
(R))
Kumar, S. Shravan; Reddy, N. Dastagiri; Roesky,
Herbert W.; Vidovic, Denis; Magull, Joerg; Winter, Rainer F. Synthesis, Structure, and Cyclic
Voltammetric Studies of [CpFeC5H4C.tplbond.CAlNCH2(C4H3S)]6: The First Model
Compound for the Fixation of Metal-Containing Ligands on an Aluminum Nitride
Cluster. Organometallics (2003), 22(17),
3348-3350. CODEN: ORGND7 ISSN:0276-7333. CAN 139:246110
AN 2003:557412
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Schiefer, Marcus; Reddy, N. Dastagiri; Ahn,
Hans-Juergen; Stasch, Andreas; Roesky, Herbert W.; Schlicker, A. Christine;
Schmidt, Hans-Georg; Noltemeyer, Mathias; Vidovic, Denis. Neutral and Ionic Aluminum, Gallium,
and Indium Compounds Carrying Two or Three Terminal Ethynyl Groups. Inorganic Chemistry (2003), 42(16),
4970-4976. CODEN:
INOCAJ ISSN:0020-1669. CAN 139:230803 AN 2003:528702 CAPLUS (Copyright 2003 ACS on SciFinder
(R))
Neculai, Dante; Mirela Neculai, Ana; Roesky, Herbert
W.; Herbst-Irmer, Regine; Walfort, Bernhard; Stalke, Dietmar. Vanadium complexes incorporating the
b-diketiminato ligand L. Syntheses and structures of
LV(OSO2CF3)2 and LVPPh2. Dalton
Transactions (2003), (14), 2831-2834.
CODEN: DTARAF
ISSN:1477-9226. AN
2003:523515
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Roesky, H. W.; Atwood, D. A.; Editors. Group 13 Chemistry III: Industrial
Applications. [In: Struct. Bonding (Berlin, Ger.), 2003; 105]. (2003), 207 pp. AN 2003:478784 CAPLUS (Copyright 2003 ACS on SciFinder
(R))
Bai, Guangcai; Roesky, Herbert W.; Li, Jiyang; Labahn,
Thomas; Cimpoesu, Fanica; Magull, Joerg.
Synthesis, Structural Characterization, and Theoretical Treatment of
an Unusual Organozirconium Hydroxide with the [Zr6(m4-O)(m-O)4(m-OH)8] Core.
Organometallics
(2003), 22(15), 3034-3038. CODEN: ORGND7
ISSN:0276-7333. CAN 139:180184
AN 2003:463840
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Madalan, Augustin M.; Voronkova, Violeta; Galeev,
Ravil; Korobchenko, Ludmila; Magull, Jorg; Roesky, Herbert W.; Andruh,
Marius. Exchange interactions
at the supramolecular level - synthesis, crystal structure, magnetic
properties, and EPR spectra of [Mn(MAC)(TCNQ)2] (MAC = pentaaza macrocyclic
ligand; TCNQ×- = radical anion of
7,7,8,8-tetracyano-p-quinodimethane).
European Journal of Inorganic Chemistry (2003),
(10), 1995-1999. CODEN: EJICFO ISSN:1434-1948. AN 2003:446494 CAPLUS (Copyright 2003 ACS on SciFinder (R))
Roesky, Herbert W.; Haiduc, Ionel; Hosmane, Narayan
S. Organometallic Oxides of
Main Group and Transition Elements Downsizing Inorganic Solids to Small
Molecular Fragments.
Chemical Reviews (Washington, DC, United States) (2003), 103(7),
2579-2595. CODEN:
CHREAY ISSN:0009-2665. CAN 139:117459 AN 2003:406889 CAPLUS (Copyright 2003 ACS on SciFinder
(R))
Neculai, Dante; Roesky, Herbert W.; Neculai, Ana
Mirela; Magull, Joerg; Herbst-Irmer, Regine; Walfort, Bernhard; Stalke,
Dietmar. The First b-Diketiminato Complex of Terbium Containing Two Alkyl
Groups: A Model Compound for LLnR2 (Ln = Lanthanide, R = Alkyl) Systems.
Organometallics
(2003), 22(11), 2279-2283. CODEN: ORGND7
ISSN:0276-7333. CAN 139:53112
AN 2003:333538
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Bai, Guangcai; Peng, Ying; Roesky, Herbert W.; Li,
Jiyang; Schmidt, Hans-Georg; Noltemeyer, Mathias. Aluminum dihydroxide with terminal OH groups: An
unprecedented congener of boronic acid. Angewandte Chemie, International
Edition (2003), 42(10), 1132-1135.
CODEN: ACIEF5
ISSN:1433-7851. CAN 139:94215
AN 2003:243806
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Bai, Guangcai; Ma, Qingjun; Roesky, Herbert W.;
Vidovic, Denis; Herbst-Irmer, Regine.
New synthetic route for organic polyoxometallic clusters: synthetic
and structural investigations on the first dumb-bell shaped polyoxozirconium
hydroxide with the [Zr9(m5-O)2(m3-O)4(m-O)4(m-OH)8] core structure.
Chemical Communications (Cambridge, United Kingdom) (2003), (7),
898-899. CODEN:
CHCOFS ISSN:1359-7345. AN 2003:238756 CAPLUS (Copyright 2003 ACS on SciFinder (R))
Ding, Yuqiang; Ma, Qingjun; Roesky, Herbert W.; Uson,
Isabel; Noltemeyer, Mathias; Schmidt, Hans-Georg. Syntheses, structures and properties of
[{HC(CMeNAr)2}Ge(E)X] (Ar = 2,6-iPr2C6H3; E = S, Se; X = F, Cl). Dalton Transactions (2003), (6),
1094-1098. CODEN: DTARAF ISSN:1477-9226. CAN 139:126800 AN 2003:202309 CAPLUS (Copyright 2003 ACS on SciFinder
(R))
Roesky, Herbert W.; Bai, Guangcai; Jancik, Vojtech;
Stasch, Andreas. Molecular
hydroxides and hydrides of aluminum. Abstracts of Papers, 225th ACS National Meeting,
New Orleans, LA, United States, March 23-27, 2003 (2003), INOR-497. CODEN: 69DSA4
AN 2003:183540
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Reddy, N. Dastagiri; Kumar, S. Shravan; Roesky,
Herbert W.; Vidovic, Denis; Magull, Jorg; Noltemeyer, Mathias; Schmidt,
Hans-Georg. Synthesis of a
hexadentate hexameric aluminum imide and its metathesis reactions. European Journal of
Inorganic Chemistry (2003), (3), 442-448. CODEN:
EJICFO ISSN:1434-1948. CAN 139:36630
AN 2003:147237
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Nikiforov, Grigori B.; Roesky, Herbert W.; Magull,
Jorg; Noltemeyer, Mathias; Schmidt, Hans-Georg; Ilyin, Evgeny G.; Kokunov, Yuri
B.; Demsar, Alojz. Synthesis
and structure of the first non-metallocene TiIII fluoride complex LTiF2×2Me3SnCl supported by a b-diketiminato ligand. European Journal of Inorganic
Chemistry (2003), (3), 437-441. CODEN:
EJICFO ISSN:1434-1948. CAN 138:401845
AN 2003:147236
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Nikiforov, Grigori B.; Roesky, Herbert W.; Labahn,
Thomas; Vidovic, Denis; Neculai, Dante.
Synthesis and structure of the first holmium and erbium diiodide
complexes of composition LLnI2 (Ln = Ho, Er). European Journal of Inorganic Chemistry (2003), (3),
433-436. CODEN:
EJICFO ISSN:1434-1948. CAN 138:394918
AN 2003:147235
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Pevec, Andrej; Perdih, Franc; Kosmrlj, Janez; Modec,
Barbara; Roesky, Herbert W.; Demsar, Alojz. Lithium complexes with a [Cp*2Ti2F7]- ligand: 19F NMR
probe for lithium solvation. Dalton Transactions (2003),
(3), 420-425. CODEN: DTARAF ISSN:1477-9226.
CAN 139:85451 AN
2003:126088 CAPLUS (Copyright 2003 ACS on SciFinder
(R))
Hohmeister,
Holger; Wessel, Helge; Lobinger, Peter; Roesky, Herbert W.; Muller, Peter;
Uson, Isabel; Schmidt, Hans-Georg; Noltemeyer, Mathias; Magull, Jorg. Stepwise fluorination of [MeAlN(2,6-i-Pr2C6H3)]3 using
trimethyltin fluoride as fluorinating agent.
Journal of Fluorine Chemistry
(2003), 120(1), 59-64. CODEN: JFLCAR ISSN:0022-1139.
CAN
139:53150 AN 2003:114685 CAPLUS (Copyright 2003 ACS on SciFinder
(R))
Pevec, Andrej; Mrak, Maja; Demsar, Alojz; Petricek,
Sasa; Roesky, Herbert W.. Coordination
number 12 in praseodymium and 11 in neodymium complexes with
organofluorotitanate ligands. Polyhedron
(2003), 22(4), 575-579. CODEN: PLYHDE
ISSN:0277-5387. AN
2003:107434
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Ackerhans, Carsten; Roesky, Herbert W.; Vidovic,
Denis; Magull, Jorg. Symmetric
tetraalkynyldisilanes.
European Journal of Inorganic Chemistry (2003),
(1), 66-69. CODEN: EJICFO ISSN:1434-1948. CAN 138:354022
AN 2003:54562
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Anantharaman, Ganapathi; Roesky, Herbert W.; Schmidt,
Hans-Georg; Noltemeyer, Mathias; Pinkas, Jiri. Synthesis and X-ray Crystal Structure of
[(THF)Zn(O2(OH)SiR)]4 (R = (2,6-i-Pr2C6H3)N(SiMe3)): Enroute to Larger
Aggregates. Inorganic
Chemistry (2003), 42(4), 970-973. CODEN:
INOCAJ ISSN:0020-1669. CAN 138:255359 AN 2003:49648 CAPLUS (Copyright 2003 ACS on SciFinder (R))
Roesky,
Herbert W.; Andruh, Marius. The interplay of coordinative, hydrogen bonding and p-p stacking interactions in sustaining supramolecular solid-state
architectures. A study case of bis(4-pyridyl)- and bis(4-pyridyl-N-oxide)
tectons. Coordination Chemistry
Reviews (2003), 236(1-2), 91-119. CODEN:
CCHRAM ISSN:0010-8545. CAN 138:377952
AN 2003:48891
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Jancik, Vojtech; Peng, Ying; Roesky, Herbert W.; Li,
Jiyang; Neculai, Dante; Neculai, Ana M.; Herbst-Irmer, Regine. The First Structurally Characterized
Aluminum Compound with Two SH Groups: [LAl(SH)2] (L = N(Ar)C(Me)CHC(Me)N(Ar),
Ar = 2,6-i-Pr2C6H3) and the Catalytic Properties of the Sulfur P(NMe2)3 System. Journal of the American Chemical Society (2003), 125(6),
1452-1453. CODEN:
JACSAT ISSN:0002-7863. CAN 138:230977
AN 2003:45642
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Gorol,
Michael; Moesch-Zanetti, Nadia C.; Roesky, Herbert W.; Noltemeyer, Mathias;
Schmidt, Hans-Georg. Unprecedented stabilization of the Ag22+-ion by two
hydrido-iridium(III) complexes. Chemical
Communications (Cambridge, United Kingdom) (2003),
(1), 46-47. CODEN: CHCOFS ISSN:1359-7345. CAN 139:6993
AN 2003:22303
CAPLUS (Copyright
2003 ACS on SciFinder (R))
Schiefer Marcus; Reddy N Dastagiri; Ahn Hans-Jurgen;
Stasch Andreas; Roesky Herbert W; Schlicker A Christine; Schmidt Hans-Georg;
Noltemeyer Mathias; Vidovic Denis Neutral
and ionic aluminum, gallium, and indium compounds carrying two or three
terminal ethynyl groups.
INORGANIC CHEMISTRY (2003
Aug 11), 42(16), 4970-6. Journal
code: 0366543.
ISSN:0020-1669. DN 22777922 PubMed ID 12895122 AN 2003382240 In-process for MEDLINE
(Copyright 2003 U.S. National Library of Medicine on SciFinder (R))
Roesky Herbert W; Haiduc Ionel; Hosmane Narayan S Organometallic oxides of main group
and transition elements downsizing inorganic solids to small molecular
fragments. CHEMICAL
REVIEWS (2003 Jul), 103(7), 2579-95. Journal code: 2985134R. ISSN:0009-2665. DN 22733378 PubMed ID 12848580 AN
2003342844 MEDLINE
(Copyright 2003 U.S. National Library of Medicine on SciFinder (R))
Bai Guangcai; Peng Ying; Roesky Herbert W; Li Jiyang;
Schmidt Hans-Georg; Noltemeyer Mathias
Aluminum dihydroxide with terminal OH groups: an unprecedented
congener of boronic acid.
ANGEWANDTE CHEMIE. INTERNATIONAL ED. IN ENGLISH
(2003 Mar 10), 42(10), 1132-5. Journal code: 0370543.
ISSN:0570-0833. DN 22525981
PubMed ID 12640641 AN 2003237610 In-process for MEDLINE (Copyright 2003 U.S.
National Library of Medicine on SciFinder (R))
Bai Guangcai; Ma Qingjun; Roesky Herbert W; Vidovic
Denis; Herbst-Irmer Regine New
synthetic route for organic polyoxometallic clusters: synthetic and structural
investigations on the first dumb-bell shaped polyoxozirconium hydroxide with
the [Zr9(mu5-O)2(mu3-O)4(mu-O)4(mu-OH)8] core structure. Chem Commun (Camb)
(2003 Apr 7), (7), 898-9. Journal code: 9610838.
ISSN:1359-7345. DN 22624592 PubMed ID 12739667 AN
2003218264 MEDLINE
(Copyright 2003 U.S. National Library of Medicine on SciFinder (R))
Gorol Michael; Mosch-Zanetti Nadia C; Roesky Herbert
W; Noltemeyer Mathias; Schmidt Hans-Georg
Unprecedented stabilisation of the Ag2(2+)-ion by two
hydrido-iridium(III) complexes. Chem Commun (Camb) (2003 Jan 7),
(1), 46-7. Journal code: 9610838.
ISSN:1359-7345. DN 22498467 PubMed ID 12610958 AN 2003098894 MEDLINE (Copyright 2003
U.S. National Library of Medicine on SciFinder (R))
Anantharaman Ganapathi; Roesky Herbert W; Schmidt
Hans-Georg; Noltemeyer Mathias; Pinkas Jiri Synthesis and x-ray crystal structure of
[(THF)Zn(O(2)(OH)SiR)](4) (R = (2,6-i-Pr(2)C(6)H(3))N(SiMe(3))): enroute to
larger aggregates.
INORGANIC CHEMISTRY (2003
Feb 24), 42(4), 970-3. Journal
code: 0366543.
ISSN:0020-1669. DN 22476702 PubMed ID 12588127 AN 2003077885 MEDLINE (Copyright 2003
U.S. National Library of Medicine on SciFinder (R))
Jancik Vojtech; Peng Ying; Roesky Herbert W; Li
Jiyang; Neculai Dante; Neculai Ana M; Herbst-Irmer Regine The first structurally characterized
aluminum compound with two SH groups: [LAl(SH)(2)] (L = N(Ar)C(Me)CHC(Me)N(Ar),
Ar = 2,6-i-Pr(2)C(6)H(3)) and the catalytic properties of the sulfur
P(NMe(2))(3) system.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003 Feb 12),
125(6), 1452-3. Journal code: 7503056.
ISSN:0002-7863. DN 22456761 PubMed ID 12568585 AN 2003058812 MEDLINE (Copyright 2003
U.S. National Library of Medicine on SciFinder (R))